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The contents of this glossary are provided for informational purposes
only; no warranty is expressed or implied.
ALPHA-BOOKMARKED INDEX:
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K - L - M -
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U - V - W -
Z
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Ablation process of removal by erosion, melting, evaporation, or vaporization.
Abrasion a wearing, grinding or rubbing away by friction,
usually (but not always) involving the action of particles against or between surfaces.
Absolute (Dynamic) Viscosity the ratio of shear stress to
shear rate, representing a fluid's internal resistance to flow. Although
the fundamental unit of absolute or dynamic viscosity is the poise,
results are often expressed in centipoise (cP). 1
centipoise equals .01 poise.
Accumulator an in-line vessel that stores fluid under
pressure for later release; used in some larger hydraulic systems.
Accuracy the closeness of a measured result to the actual (true) value.
Acid any one of various hydrogen-containing molecules or ions
capable of giving up a proton to a base, of accepting an unshared pair
of electrons from a base, or of reacting with a base to form a salt. A
more limited definition restricts the acid to a hydrogen-containing
substance that contains a non-metallic radical and produces hydrogen
ions when placed in solution.
Acid digestion process of dissolving a sample in an acid
matrix, usually accompanied by heating.
Acid treating A refining process where unfinished petroleum
products (gasoline, kerosene, lube oil stocks, etc.) are brought into
contact with sulfuric acid to improve their color, odor, and other
properties.
Acidity specific to oil analysis, acidity denotes the
presence of weakly and strongly acidic materials whose total
concentration is usually defined in terms of the TAN (Total Acid
Number).
Active metal a metal ready to corrode, or being corroded.
Contrast with noble metal.
Additives An agent added to oils, fuels, and coolants to
impart specific beneficial properties to the finished products.
Additives create new fluid properties, enhance properties already
present and reduce the rate at which undesirable changes take place in a
fluid during service. Selected additives are:
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TYPE |
PURPOSE |
TYPICAL COMPOUNDS |
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Dispersants, Detergents |
keep sludge, carbon and other deposit precursors suspended |
succinimides, neutral metallic sulfonates, phenates, polymeric
detergents, amines |
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Basic Metal Compounds |
neutralize acids, prevent corrosion |
overbased metallic sulfonates, phenates, carbonates |
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Oxidation Inhibitors |
prevent or control oxidation of oil by forming oxygen-inactive
compounds and / or scavenging free oxygen |
zinc dialkyldithiophosphates; aromatic amines, sulfurized
products, hindered phenols |
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Extreme Pressure (EP) Antiwear Additives |
reduce wear, prevent scuffing and seizing by forming protective
surface films |
zinc dialkyldithiophosphates; tricresylphosphates, organic
phosphates, chlorine and sulfur compounds |
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Viscosity Index Improvers |
reduce the rate of viscosity change with temperature |
polyisobutylene, methacrylate polymers, olefin copolymers- may
incorporate dispersants |
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Rust Inhibitors |
prevent the formation of rust on metal surfaces by formation of
surface film or neutralization of acids |
high base additives, sulfonates, phosphates, organic acids or
esters, amines |
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Corrosion Inhibitors |
prevent corrosive attack on alloy bearings or other metallic
surfaces |
organically active sulfur, phosphorus, nitrogen compounds such
as phosphites, metal salts of thiophosphoric acid, sulfurized
waxes, terpenes |
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Antifoamants |
reduce foam with surface tension modifiers that break up large
surface bubbles, or small entrained bubble reducers |
silicones, organic polymers |
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Friction Modifiers |
reduce or modify friction |
long chain polar compounds, (amides, phosphates, phosphites,
acids, etc.), molybdenum disulfides |
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Metal Deactivators |
form surface films so metal surfaces do not catalyze oil
oxidation |
zinc dialkyldithiophosphates, metal phenates, organic nitrogen
compounds |
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Pour Point Depressants |
lower "freezing" point of oils assuring free flow at
low temperatures |
low molecular weight methacrylate polymers |
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Emulsifiers |
permit water-in-oil or oil-in-water emulsions by changing
interfacial tension |
soaps of fatty acids, sulfonic or napthenic acids |
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Demulsifiers |
lower emulsion stability |
heavy metal soaps, alkaline earth sulfonates |
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Tackiness Agents |
increase adhesiveness of lubricant on metal surfaces; reduce
runoff |
high molecular weight polymers, aluminum soaps of unsaturated
fatty acids |
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Oiliness Agents |
lower friction under near-boundary conditions |
high molecular weight polar compounds such as fatty oils,
oxidized waxes or soaps |
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Adhesion the force of molecular attraction exerted between
two surfaces in contact.
Absorption the process by which one substance draws itself
into another substance. An example is a sponge picking up water, or on
oil recovering gasoline from wet natural gas.
Adsorption the adhesion of an extremely thin layer of
molecules (gases, dissolved solids, or liquids) to the surfaces of
solids or liquids with which the molecules are in contact. This process
is utilized in a broad range of fluid and additive applications to
concentrate one material on the surface of another.
Aeration combining or charging a fluid with a gas, as in oil
being aerated with air.
Aerosol a highly dispersed suspension of fine solid or liquid
particles in a gas.
Aftercooling the process of cooling compressed gases under
constant pressure after the final stage of compression.
Agglomeration the action of combining a number of small
particles into a larger single mass, often the operating principle for
additives which promote particle attraction and clumping.
Air entrainment The incorporation of air (bubbles) as a
dispersed phase in a liquid. Air entrainment may result from mechanical
means or by sudden environmental changes. The presence of entrained air
is usually obvious from the hazy, opaque, or bubbly physical appearance
of the liquid while dissolved air can only be determined by
specific testing.
Alkali any substance having basic (as opposed to acidic)
properties. A more limited definition restricts the alkali to hydroxides
of ammonium, lithium, potassium and sodium.
Alloy steel steel containing specified quantities of alloying
elements added to effect changes in mechanical or physical properties.
Ambient temperature temperature of the area or atmosphere around a process, (not the operating temperature of
the process itself).
Anhydrous free of water, especially water of crystallization
(water present as an internal part of the structure of a salt crystal).
Aniline point the minimum temperature for complete miscibility of equal volumes of aniline and the sample. A
product of high aniline point will be Iow in aromatics and naphthenes
and, therefore, high in paraffins. Aniline point is often specified for
spray oils, cleaning solvents, and thinners, where effectiveness depends
upon aromatic content. In conjunction with API gravity, the aniline
point may be used to calculate the net heat of combustion for aviation
fuels.
Annealing a generic term denoting a treatment consisting of heating a metal to a suitable temperature and holding it
there, followed by cooling at a suitable rate. This process is used
primarily to soften metallic materials, but also to simultaneously
produce desired changes in the metals microstructure or other
properties. When the term is used by itself, full annealing is
implied. When the treatment is applied only for the relief of stress, it
is properly called stress-relieving or stress-relief
annealing.
Anodizing forming a conversion coating on a
metal surface by anodic (electron-removing) oxidation; most frequently
applied to aluminum.
Apparent viscosity The ratio of shear stress to rate of shear
of a non-Newtonian fluid such as lubricating grease, calculated from
Poiseuille's equation and measured in poises. The apparent viscosity
changes with changing rates of shear and temperature and must,
therefore, be reported as the value at a given shear rate and
temperature.
API engine service categories gasoline and diesel engine oil
quality levels established jointly by API, SAE, and ASTM, and sometimes
called SAE or API/SAE categories; formerly called API Engine Service
Classifications.
API gravity a gravity scale established by the American
Petroleum Institute and in general use in the petroleum industry, the
unit being called "the API degree", which is represented by
the equation:
API gravity, deg = (141.5/specific gravity at 60/60ºF)-131.5
API base stock base fluid for automotive engine oils. The API
(American Petroleum Institute) currently designates five classes of base
stocks. These stock types are independent of crude source or processing.
Instead, they are based on physical characteristics of the base stock,
which are then related to formulated engine oil performance:
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GROUP |
CHARACTERISTICS |
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Group I |
Contain <90% saturates and/or >0.03% sulfur, with
viscosity index ³ 80 and
<120. Commonly referred to as conventional, solvent refined base
stocks.
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Group II |
Contain ³ 90% saturates and
£ 0.03% sulfur, with viscosity
index ³ 80 and <120.
Commonly referred to as severely hydrotreated and/or
hydrocracked base stocks.
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Group III |
Contain ³ 90% saturates,
with £ 0.03% sulfur, with
viscosity index ³ 120.
Commonly referred to as VHVI or XHVI base stocks.
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Group IV |
PAO's (polyalphaolefins) |
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Group V |
All other base stocks not included in Groups I, II, III, or IV. |
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(where < stands for less than, £
stands for less than or equal to, ³
stands for greater than or equal
to, and > stands for greater than)
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Aromatic derived from, or characterized by, the presence of
the benzene ring.
Ash a measure of the amount of inorganic material in
lubricating oil. Determined by burning the oil and weighing the residue.
Asperities microscopic projections on metal surfaces.
Asperities result from normal finishing processes or from any other
process or condition which changes the surface profile. Interference
between opposing asperities in sliding or rolling wear is a source of
friction, and can lead to metal welding and scoring. Ideally, the
lubricating film between two moving surfaces should be thicker than the
combined height of the opposing asperities.
Auto-ignition point The temperature at which a
substance ignites without other sources of energy. Also, associated with
the spontaneous ignition and sustained combustion of part or all of the
fuel-air mixture in an engine. The flame speed is many times greater
than that associated with normal spark ignition, producing a
characteristic "knocking" sound.
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ALPHA-BOOKMARKED INDEX:
A - B - C -
D - E - F -
G - H - I -
K - L - M -
N - O - P -
R - S - T -
U - V - W -
Z
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